米糠不溶性膳食纤维和阿魏酸共同作用对籼米淀粉糊化过程的影响

    The effect of rice bran insoluble dietary fiber and ferulic acid on the gelatinization process of indica rice starch

    • 摘要: 通过向籼米淀粉中添加米糠不溶性膳食纤维和阿魏酸,测定体系的黏度、流变学、碘结合以及热力学特性,探究两种物质共同作用对籼米淀粉糊化过程的影响。研究发现不溶性膳食纤维和阿魏酸在限制籼米淀粉颗粒的自由膨胀、减弱淀粉形成凝胶、降低淀粉的短期老化程度、提升淀粉糊的热稳定性、提高淀粉的糊化温度和延长淀粉的糊化时间上具有“协同”趋势。不溶性膳食纤维会削弱淀粉高温耐剪切性能,而阿魏酸有增强的趋势。不溶性膳食纤维和阿魏酸对淀粉动态流变-温度扫描曲线以及流变学各项参数影响显著。不溶性膳食纤维具有降低碘结合力和减小最大吸收波长的趋势,阿魏酸会产生一定的“拮抗”趋势。不溶性膳食纤维具有提升碘蓝值的趋势,而阿魏酸在低添加量时具有“协同”趋势,高添加量时具有“拮抗”趋势。不溶性膳食纤维具有提升糊化起始温度(To)、糊化峰值温度(TP)、糊化终止温度(TC)和降低糊化焓值(ΔH)的趋势,阿魏酸具有“协同”趋势。

       

      Abstract: Rice bran is the surface layer that is crushed during the whitening process of brown rice. The mixture of rice germ and broken rice accounts for about 6% of the weight of rice. Rice bran is defatted rice bran after leaching or squeezing oil rich in dietary fiber, and its total amount accounts for about 30%-50% of the weight of defatted rice bran. The dietary fiber in defatted rice bran is almost water-insoluble dietary fiber, and its main components are cellulose, hemicellulose, and lignin. Rice bran contains many phenolic acids, and the most abundant is ferulic acid. This study determined the effects of rice bran insoluble dietary fiber and ferulic acid on the gelatinization, rheology, swelling, and thermal properties of rice starch. It is found that rice bran insoluble dietary fiber and ferulic acid have different effects on the gelatinization process of rice starch. The effect of insoluble dietary fiber on the gelatinization process of rice starch is mainly reflected in the hydration that competes with starch molecules and the physical obstacles to the starch network structure. The effect of ferulic acid on the gelatinization process of rice starch is more complicated as follows. First, ferulic acid competes with starch for water molecules. Second, ferulic acid forms a complex with amylopectin. Third, ferulic acid forms an inclusion compound with amylose. Fourth, ferulic acid causes irreversible acidolysis of starch. Fifth, ferulic acid changes the electronegativity, water activity, and ionic strength of the system. This series of complex reactions leads to the influence of water-insoluble dietary fiber and ferulic acid on the gelatinization process of rice starch, which has a tendency of "synergy" and "antagonism". Water-insoluble dietary fiber and ferulic acid limit the free swelling of rice starch granules, weaken the formation of starch gel, reduce the short-term aging degree of starch, improve the thermal stability of starch paste, increase the starch gelatinization temperature, and extend the time length of starch gelatinization. The "synergy" trend on the Internet. Water-insoluble dietary fiber has a tendency to weaken the high temperature shear strength of starch, while ferulic acid has a tendency to enhance the high temperature shear strength of the system. At this time, both substances have a certain "antagonistic" trend. Water-insoluble precipitated fiber and ferulic acid have significant effects on the dynamic rheology-temperature scan curve and rheological parameters of starch. Water-insoluble dietary fiber has a tendency to reduce the binding capacity of iodine and the maximum absorption wavelength, and ferulic acid will have a certain "antagonistic" tendency. Water-insoluble dietary fiber has a tendency to increase the value of iodine blue, while ferulic acid has a "synergistic" tendency at low doses, and a "antagonistic" tendency at high doses. Water-insoluble dietary fiber has a tendency to increase To, TP, TC and decrease ΔH, while ferulic acid has a "synergistic" tendency in these four aspects. This article focuses on the analysis of the effects of water-insoluble dietary fiber and ferulic acid on the starch gelatinization process, but whether there is a reaction between water-insoluble dietary fiber and ferulic acid and whether this reaction affects the starch gelatinization process remains to be studied.

       

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