湿磨辅助制备淀粉-脂质复合物及其结构和性能研究

    Preparation of starch-lipid complex assisted by wet grinding and its structure and properties analysis

    • 摘要: 基于湿磨在改善淀粉性能方面具有良好的潜力,探究湿磨对淀粉-脂质复合物结构和性质的影响。以玉米淀粉与月桂酸为原料,采用先复合后湿磨(C/WG)和先湿磨后复合(WG/C)两种处理方式制备淀粉-脂质复合物。X射线衍射结果显示未进行湿磨处理的对照组、先复合后湿磨组(CS-C/WG)和先湿磨后复合组(CS-WG/C)样品具有强烈的V型晶体特征衍射峰;傅里叶变换红外光谱显示样品在2 850 cm-1和1 740 cm-1处出现了两个新的吸收峰,表明玉米淀粉和月桂酸形成了淀粉-脂质复合物;与对照组相比,CS-WG/C和CS-C/WG表现出了更高的复合指数、V型晶体特征衍射峰强度与焓变值,并且,先湿磨后复合的制备方式更有利于形成更多的淀粉-脂质复合物。湿磨可显著提高淀粉的热稳定性和抗消化性,且适当的湿磨处理有助于促进淀粉-脂质复合物的形成。

       

      Abstract: Based on the good potential of wet grinding in improving starch properties, this study aimed to explore the effect of wet grinding on the structure and properties of starch-lipid complexes. Corn starch and lauric acid were used as raw materials, and starch-lipid complex was prepared by the two treatment methods of compound before wet grinding (C/WG) and wet grinding before compound (WG/C). X-ray diffraction results showed that Control, CS-WG/C and CS-C/WG samples represented strong V-type crystal characteristic diffraction peaks. Fourier-transform infrared showed that samples had two new absorption peaks at 2 850 cm-1 and 1 740 cm-1. Control had the endothermic peak of type I complex at 87-95℃ and type Ⅱ complex at 107-113℃. CS-WG/C and CS-C/WG had an endothermic peak of type Ⅱ complex at 106-122℃. These results confirmed the formation of starch-lipid complexes between corn starch and lauric acid. Meanwhile, with the increase of wet grinding time from 0 min to 10 min, the composite index, the intensity of V-type crystal characteristic diffraction peak, T'p, T'c and ΔH' of CS-WG/C and CS-C/WG gradually increased. It suggested that proper wet grinding treatment could promote the formation of starch-lipid complex. In addition, compared with CS-C/WG at the same WG time, CS-WG/C granules showed a higher composite index, V-type crystal characteristic diffraction peak intensity and ΔH'. It was thus clear that WG/C was more beneficial to the formation of more starch-lipid complexes. The formation of starch-lipid complex endowed starch with higher thermal stability and lower digestibility, solubility and swelling power. CS-WG/C-10 had the highest content of resistant starch (36.32%), the lowest solubility (3.9%) and the lowest swelling power (7.8 g/g). This study could provide a theoretical basis for the application of wet grinding treatment in the production of starch lipid complexes.

       

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