花生硬脂的性质研究

    Study on the properties of peanut stearins

    • 摘要: 为解决花生硬脂(peanut stearin,PeS)目前存在的研究不足、应用局限及附加值低等问题,以工厂中花生油冬化产物(3种PeS)为原料,对其理化性质进行分析,并利用差示扫描量热法、X射线衍射及偏光显微镜对其热力学性质、同质多晶性质和晶体微观形态进行研究。结果表明:PeS的脂肪酸组成以油酸(O,31.56%~35.77%)、亚油酸(L,33.40%~35.98%)、棕榈酸(P,11.94%~14.11%)和硬脂酸(St,7.00%~8.83%)为主,此外,还含有部分二十碳及以上的超长链脂肪酸(9.33%~12.12%);PeS的碘值(IV)为85.33~93.53 g/100 g;0~25 ℃时PeS的滑动熔点随IV的降低而升高;PeS分别在-30~0 ℃和0~25 ℃出现了2个较强、较宽的吸热峰,在-20~20 ℃出现了1个较宽的放热峰;PeS晶型为β'型,晶体形态为羽毛叶片状,晶簇呈花瓣状聚集;15 ℃时PeS的等温结晶行为均为一步结晶,但其滞后期有所不同。PeS通过与其他硬脂混合或酯交换,可用作塑性脂肪的基料油。

       

      Abstract: Peanut stearins (PeS), the winterisation product of peanut oil in the plant, were used as raw materials to study their properties and to solve the problems of insufficient research, limited application and low added value of PeS. The physicochemical properties of the three PeS were analysed, and their thermodynamic properties, crystal polymorphism and crystal micromorphology were investigated by differential scanning calorimetry (DSC), X-ray diffraction and polarized light microscopy.The major fatty acids of PeS determined by gas chromatography were oleic (O, 31.56%-35.77%), linoleic (L, 33.40%-35.98%) and palmitic (P, 11.94%-14.11%) acids, followed by stearic (St, 7.00%-8.83%), behenic (Be,4.69%-6.27%), arachidic (Ad,2.74%-3.52%), lignoceric (1.31%-1.89%) and eicosenoic (0.44%-0.59%) acids, and the iodine values (IVs) of PeS were in the range of 85.33-93.53 g/100 g. PeS is mainly composed of tri-unsaturated triglycerides and mono-saturated di-unsaturated triglycerides. Due to the high content of unsaturated triglycerides, PeS had relativelly low SFC and crystallized slowly. In the range of 0-25 ℃, SFCs of PeS increased with the saturated fatty acids increasing at a given temperature. The slip melting points of PeS increased with IV decreasing and ranged from 22.1 ℃ to 26.3 ℃. The results of the thermal analysis exhibited that PeS showed two strong and wide endothermic peaks in the range of -30-0 ℃ and 0-25 ℃ in the melting process while presenting one wide exothermic peak in the range of -20-20 ℃ during the crystallization process. Two distinct diffraction peaks close to 4.10 and 3.70 Å presented in PeS were attributed to the β' form crystal. The crystal cluster of PeS with lower IV was feather blade-like and the aggregates of the clusters of them were rosette-like. However, PeS with higher IV showed cloud-like morphology. PeS exhibited one-step crystallization with various lag periods at 15 ℃. PeS could be used as base stock in plastic fat preparation through blending or interesterification with other hard fats.

       

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